{"id":62550,"date":"2023-12-15T06:00:47","date_gmt":"2023-12-14T22:00:47","guid":{"rendered":"http:\/\/learncmg.cn\/?p=62550"},"modified":"2023-12-15T06:00:47","modified_gmt":"2023-12-14T22:00:47","slug":"%ef%bc%886%ef%bc%89%e6%b8%a9%e5%ae%a4%e6%b0%94%e4%bd%93%e9%80%89%e9%a1%b9-%e5%8f%8d%e5%ba%94%e5%b9%b3%e8%a1%a1%e5%8f%8a%e9%80%9f%e7%8e%87%e5%8f%82%e6%95%b0","status":"publish","type":"post","link":"http:\/\/learncmg.cn\/?p=62550","title":{"rendered":"\uff086\uff09\u6e29\u5ba4\u6c14\u4f53\u9009\u9879 – \u53cd\u5e94\u5e73\u8861\u53ca\u901f\u7387\u53c2\u6570"},"content":{"rendered":"
\n

GHG Option – Reaction Equilibrium and Rate Parameters<\/h3>\n

\u76ee\u7684<\/h3>\n

\u8fd9\u4e9b\u5173\u952e\u8bcd\u7528\u4e8e\u5b9a\u4e49\u7528\u4e8e\u6c34\u76f8\u5316\u5b66\u5e73\u8861\u53cd\u5e94\u548c\u77ff\u7269\u6eb6\u89e3\u53ca\u6c89\u6dc0\u53cd\u5e94\u7684\u53c2\u6570\u3002<\/p>\n

\u683c\u5f0f<\/h3>\n\n\n\n<\/colgroup>\n\n\n\n\n\n\n\n\n
\n

*LOG-CHEM-EQUIL-CONST<\/p>\n

*LOG-CHEM-EQUIL-COEFS<\/p>\n

*REACTIVE-SURFACE-AREA<\/p>\n<\/td>\n

\n

Keq<\/p>\n

a0\u00a0\u00a0a1\u00a0\u00a0a2\u00a0\u00a0a3\u00a0\u00a0a4<\/p>\n

area0<\/p>\n<\/td>\n<\/tr>\n

\n

*SPEC-REACT-SURFACE-AREA<\/p>\n

*MIN-REACT-SURFACE-AREA<\/p>\n

*SUPER-SATURATION-INDEX<\/p>\n<\/td>\n

\n

area_s<\/p>\n

area_min<\/p>\n

ssi<\/p>\n<\/td>\n<\/tr>\n

\n

*LOG-TST-RATE-CONSTANT<\/p>\n

*REF-TEMP-RATE-CONST<\/p>\n<\/td>\n

\n

k0_ref<\/p>\n

t_ref<\/p>\n<\/td>\n<\/tr>\n

\n

*ACTIVATION-ENERGY<\/p>\n

*LOG-TST-RATE-CONSTANT-ACTIV<\/p>\n<\/td>\n

\n

e_act<\/p>\n

ki<\/p>\n<\/td>\n<\/tr>\n

\n

*TST-ACTIVITY-POWER<\/p>\n

*TST-PARAM1<\/p>\n

*TST-PARAM2<\/p>\n<\/td>\n

\n

omega_i<\/p>\n

tst_1<\/p>\n

tst_2<\/p>\n<\/td>\n<\/tr>\n

*REACTION-ORDER<\/td>\n\n

‘comp_name1’\u00a0\u00a0\u03b11<\/p>\n

‘comp_name2’\u00a0\u00a0\u03b12<\/p>\n

‘comp_name3’\u00a0\u00a0\u03b13<\/p>\n

\u00a0 . . \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 . .<\/p>\n<\/td>\n<\/tr>\n

*FREQUENCY-FACTOR<\/td>\nF<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u6761\u4ef6<\/h3>\n

\u5982\u679c\u5b58\u5728\u8fd9\u4e9b\u5173\u952e\u5b57\uff0c\u5219\u5fc5\u987b\u51fa\u73b0\u5728\u6d41\u4f53\u6a21\u578b\u90e8\u5206\u3002\u5173\u952e\u5b57\u00a0*REACTION-CHEM,\u00a0*REACTION-EQUIL-MNR,\u00a0*REACTION-RATE-ARN, and\u00a0*REACTION-RATE-TST\u00a0\u7528\u4e8e\u5b9a\u4e49\u5316\u5b66\u5e73\u8861\u3001\u963f\u5c14\u5c3c\u4e4c\u65af\u548c\u77ff\u7269\u6eb6\u89e3\u548c\u6c89\u6dc0\u53cd\u5e94\u7684\u914d\u5e73\u7cfb\u6570\u3002\u00a0<\/p>\n

\u5b9a\u4e49<\/h3>\n

*LOG-CHEM-EQUIL-CONST\u00a0\u00a0Keq<\/p>\n

log (Keq<\/sub>) \uff0c\u6c34\u76f8\u5316\u5b66\u5e73\u8861\u53cd\u5e94\u6216\u901f\u7387\u4f9d\u8d56\u7684\u77ff\u7269\u6eb6\u89e3\u548c\u6c89\u6dc0\u53cd\u5e94\u7684\u5316\u5b66\u5e73\u8861\u5e38\u6570\u7684\u5bf9\u6570\uff08\u4ee510\u4e3a\u5e95\uff09\u3002<\/p>\n

*LOG-CHEM-EQUIL-COEFS\u00a0\u00a0a0\u00a0\u00a0a1\u00a0\u00a0a2\u00a0\u00a0a3\u00a0\u00a0a4<\/p>\n

log (Keq) \uff0c\u7528\u6e29\u5ea6T\u7684\u56db\u9636\u591a\u9879\u5f0f\u6765\u8ba1\u7b97\uff0c\u5373\u00a0log(Keq)\u00a0a0+\u00a0a1T\u00a0+\u00a0a2T2\u00a0+\u00a0a3T3\u00a0+\u00a0a4T4\uff0c\u5176\u4e2dT\u4ee5\u00b0C\u4e3a\u5355\u4f4d\u3002\u5b83\u5fc5\u987b\u540e\u8ddf5\u4e2a\u503c\u03b1i, i = 0,1,\u2026,4.\u3002\u5982\u679c\u4f7f\u7528\u4e86\u6b64\u5173\u952e\u8bcd\uff0c\u5219\u4e0d\u9700\u8981\u00a0*LOG-CHEM-EQUIL-CONST\u3002<\/p>\n

*REACTIVE-SURFACE-AREA\u00a0\u00a0area0<\/p>\n

\"\"\"\"\"\"\u5ca9\u77f3\u4f53\u79ef\u7684\u521d\u59cb\u53cd\u5e94\u9762\u79ef\uff0c\u5355\u4f4d\u4e3am\u00b2 \/m\u00b3\u3002\u00a0<\/p>\n

*SPEC-REACT-SURFACE-AREA\u00a0\u00a0area_s<\/p>\n

\u77ff\u7269\u4f53\u79ef\u7684\u521d\u59cb\u7279\u5b9a\u53cd\u5e94\u8868\u9762\u79ef\uff0c\u5355\u4f4d\u4e3am\u00b2 \/m\u00b3\u3002area0=area_s*\uff08\u77ff\u7269\u7684\u4f53\u79ef\u5206\u6570\uff09<\/p>\n

*MIN-REACT-SURFACE-AREAarea_min<\/p>\n

\u77ff\u7269\u4f53\u79ef\u7684\u6700\u5c0f\u7279\u5b9a\u53cd\u5e94\u8868\u9762\u79ef\uff0c\u5355\u4f4d\u4e3am\u00b2 \/m\u00b3\u3002\u5982\u679c\u4e00\u4e2a\u77ff\u7269\u521d\u59cb\u65f6\u4e0d\u5b58\u5728\uff0c\u4e14\u4f7f\u7528\u4e86\u00a0*SPEC-REACT-SURFACE-AREA\uff0c\u5219\u5fc5\u987b\u8f93\u5165\u4e00\u4e2a\u6b63\u503c\u7684\u00a0area_min\uff0c\u4ee5\u5141\u8bb8\u6c89\u6dc0\u3002<\/p>\n

\u00a0*SUPER-SATURATION-INDEX\u00a0\u00a0SS<\/p>\n

\u53ef\u4ee5\u7528\u6765\u5ef6\u8fdf\u77ff\u7269\u7684\u6c89\u6dc0\u3002\u6c89\u6dc0\u6216\u6eb6\u89e3\u7531\u9971\u548c\u6307\u6570\uff08S\uff09\u63a7\u5236\u3002S <1\u8868\u793a\u6eb6\u89e3\uff0cS>1\u8868\u793a\u6c89\u6dc0\u3002\u5982\u679c\u8f93\u5165\u4e86SS\u00a0\u7684\u503c\uff08SS\u00a0>1\uff09\uff0c\u90a3\u4e481\u2264S\u2264SS\u00a0\u65f6\u5c31\u4e0d\u4f1a\u6709\u6c89\u6dc0\u3002\u3010\u65e0\u91cf\u7eb2\u3011<\/p>\n

\u8fd9\u5141\u8bb8\u77ff\u7269\u5373\u4f7f\u6700\u521d\u4e0d\u5b58\u5728\u65f6\u4e5f\u4f1a\u53d1\u751f\u6c89\u6dc0\u3002<\/p>\n

*LOG-TST-RATE-CONSTANT\u00a0\u00a0k0_ref<\/p>\n

\u00a0log\u00a0k0\u00a0[ mol\/(m2s) ]\uff0c\u6807\u51c6TST\u901f\u7387\u5e38\u6570\u3002<\/p>\n

\u00a0*REF-TEMP-RATE-CONST\u00a0\u00a0t_ref<\/p>\n

t*\u00a0(\u00b0C)\uff0c\u901f\u7387\u5e38\u6570\u7684\u53c2\u8003\u6e29\u5ea6\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=25\u00b0C\u3002<\/p>\n

*ACTIVATION-ENERGY\u00a0\u00a0e_act<\/p>\n

Ea\u00a0\u6d3b\u5316\u80fd\uff0c\u5355\u4f4d\u4e3aJ\/mol\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=0\u3002<\/p>\n

\u00a0*LOG-TST-RATE-CONSTANT-ACTIV\u00a0\u00a0ki<\/p>\n

\u00a0log\u00a0ki\u00a0[ mol\/(m2s) ], (nc\u00a0+ 1 +\u00a0nc_aqu)\u00a0\u503c\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=0\u3002<\/p>\n

\u00a0*TST-ACTIVITY-POWER\u00a0\u00a0omega_i<\/p>\n

\u03c9i, (nc\u00a0+ 1 +\u00a0nc_aqu)\u503c\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=0\u3002<\/p>\n

\u00a0*TST-PARAM1\u00a0\u00a0ts
\nt_1<\/p>\n

\u00a0\u03be, power for\u00a0Q\/Keq\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=1\u3002<\/p>\n

\u00a0*TST-PARAM2\u00a0\u00a0tst_2<\/p>\n

\u00a0\u03b6, power for | 1 – (Q\/Keq)\u03be\u00a0|\u3002\u53ef\u9009\uff0c\u9ed8\u8ba4=1\u3002<\/p>\n

\u00a0*LOG-TST-RATE-CONSTANT<\/p>\n

\u00a0log\u00a0k0\u00a0[ mol\/(m2s) ], \u6807\u51c6TST\u901f\u7387\u5e38\u6570\u3002<\/p>\n

*REACTION-ORDER<\/p>\n

\u00a0‘comp_name_i’\u00a0\u00a0\u03b1i<\/p>\n

\u53cd\u5e94\u7ec4\u5206\u540d\u79f0\u5217\u8868\uff0c\u540e\u8ddf\u53cd\u5e94\u7ea7\u6570\u3002\u5bf9\u4e8e\u77ff\u7269\u7684\u53cd\u5e94\u7ea7\u6570\u7684\u6307\u5b9a\u4e0d\u662f\u5fc5\u9700\u7684\uff08\u5982\u679c\u63d0\u4f9b\u5c06\u51fa\u73b0\u9519\u8bef\uff09\u3002\u5982\u679c\u8f93\u5165\u4e86\u503c\uff0c\u5b83\u4eec\u5c06\u7528\u4f5cArrhenius\u53cd\u5e94\u8868\u8fbe\u5f0f\"\"\u4e2d\u7684a\u3002\u5982\u679c\u672a\u4f7f\u7528\u6b64\u5173\u952e\u5b57\uff0c\u9ed8\u8ba4\u53cd\u5e94\u6b21\u5e8f\u5c06\u4e3a\u96f6\u3002<\/p>\n

\u00a0*FREQUENCY-FACTOR\u00a0\u00a0F<\/p>\n

\u9891\u7387\u56e0\u5b50\u6216\u6307\u524d\u56e0\u5b50\u7528\u4e8eArrhenius\u53cd\u5e94\u901f\u7387\u3002\u5176\u5355\u4f4d\u53d6\u51b3\u4e8e\u53cd\u5e94\u7684\u603b\u7ea7\u6570\uff0c\u4f8b\u5982\uff1a\u00a0[ 1\/(sec.molality\u00a0a-1) ]\u00a0\uff0c\u5176\u4e2da\u4e3a\u53cd\u5e94\u7684\u603b\u7ea7\u6570\u3002<\/p>\n

\"\"<\/p>\n

\u89e3\u91ca\uff1a<\/h3>\n

\u6c34\u76f8\u5316\u5b66\u5e73\u8861\u53cd\u5e94\u7531\u4e0b\u8ff0\u65b9\u7a0b\u63a7\u5236\uff1a<\/p>\n

Q\u00a0=\u00a0Keq<\/p>\n

\u5176\u4e2dQ\u662f\u7531\u6d3b\u5ea6\u4e58\u79ef\u7ed9\u51fa\u7684\uff0c<\/p>\n

\"\"<\/a><\/p>\n

Keq\u662f\u5316\u5b66\u5e73\u8861\u5e38\u6570\u3002<\/p>\n

\u7528\u4e8e\u8ba1\u7b97\u00a0\u6d3b\u5ea6\u4e58\u79ef\u7684\u6307\u6570\uff08\u00a0(vi)\u8bbe\u7f6e\u4e3a\u914d\u5e73\u7cfb\u6570\u3002\u7ec4\u5206H2O\u7684\u6307\u6570\u53d6\u96f6\u3002<\/p>\n

\u5bf9\u4e8e\u6c34\u76f8\u5316\u5b66\u5e73\u8861\u53cd\u5e94\uff0c\u4ec5\u9700\u8981\u00a0*LOG-CHEM-EQUIL-CONST\u00a0or\u00a0*LOG-CHEM-EQUIL-COEFS\u3002<\/p>\n

GEM\u63d0\u4f9b\u4e24\u79cd\u7c7b\u578b\u7684\u65b9\u7a0b\u7528\u4e8e\u6a21\u62df\u901f\u7387\u53cd\u5e94\uff0c\u5373\u8fc7\u6e21\u6001\u7406\u8bba\uff08TST\uff09\u65b9\u7a0b\u548c\u963f\u5c14\u5c3c\u4e4c\u65af\u65b9\u7a0b\u3002<\/p>\n

TST\u65b9\u7a0b\u901a\u8fc7*LOG-CHEM-EQUIL-CONST\u00a0\u6216\u00a0*LOG-CHEM-EQUIL-COEFS\u5173\u952e\u8bcd\u4e4b\u4e00\u6fc0\u6d3b\u3002\u8fd9\u4e9b\u5173\u952e\u8bcd\u4e0d\u9002\u7528\u4e8e\u963f\u5c14\u5c3c\u4e4c\u65af\u7c7b\u578b\u7684\u65b9\u7a0b\u3002<\/p>\n

\u5bf9\u4e8e\u963f\u4f26\u5c3c\u4e4c\u65af\u7c7b\u578b\u7684\u65b9\u7a0b\uff0c\u4f7f\u7528*FREQUENCY-FACTOR\u00a0and\u00a0*ACTIVATION-ENERGY\u00a0\u5173\u952e\u8bcd\uff0c\u4f46\u00a0*FREQUENCY-FACTOR\u7684\u5b58\u5728\u662f\u5f3a\u5236\u6027\u7684\u3002\u5982\u679c\u672a\u8f93\u5165<\/em>\uff0c\u5219\u9ed8\u8ba4*ACTIVATION-ENERGY\u4e3a\u96f6\u3002<\/p>\n

*REACTION-RATE-TST\u00a0\u548c\u00a0*REACTION-RATE-ARN\u7528\u4e8e\u533a\u5206TST\u548c\u963f\u5c14\u5c3c\u4e4c\u65af\u53cd\u5e94\u3002\u5bf9\u4e8eTST\u53cd\u5e94\uff0c\u5173\u952e\u8bcd*REACT-RATE\u4ecd\u7136\u53d7\u652f\u6301\uff0c\u4f46\u5df2\u88ab\u5f03\u7528\u3002<\/p>\n

\u00a0<\/p>\n

TST\u53cd\u5e94\uff1a<\/strong><\/h4>\n

\u77ff\u7269\u6eb6\u89e3\u548c\u6c89\u6dc0\u53cd\u5e94\u901f\u7387\u662f\u6839\u636e\u8fc7\u6e21\u6001\u7406\u8bba\uff08TST\uff09\u8ba1\u7b97\u7684\u3002TST\u901f\u7387\u7684\u65b9\u7a0b\u4e3a\uff1a<\/p>\n

\"\"<\/a><\/p>\n

\u5f0f\u4e2d\uff1a<\/p>\n

\"\"<\/p>\n

\"\" \u662f\u5f53\u524d\u65f6\u95f4\u7684\u53cd\u5e94\u8868\u9762\u79ef\uff0c\"\"\u662f\u65f6\u95f4\u4e3a\u96f6\u7684\u53cd\u5e94\u8868\u9762\u79ef\u3002Nm\u548cNm0\u5206\u522b\u662f\u5f53\u524d\u65f6\u523b\u7684\u77ff\u7269\u6469\u5c14\u6570\u548c\u65f6\u95f4\u4e3a\u96f6\u7684\u77ff\u7269\u6469\u5c14\u6570\u3002<\/p>\n

\u5f53\u524d\u6e29\u5ea6\u00a0T[\u00a0K\u00a0]\u4e0b\u7684\u901f\u7387\u5e38\u6570\"\"\u00a0\"\" \u53ef\u4ee5\u4ece\u901f\u7387\u5e38\u6570\u8ba1\u7b97\u5f97\u51fa\uff0c<\/p>\n

\"\"<\/p>\n

\u5bf9\u4e8e\u4e00\u4e2a\u53cd\u5e94\u6709\uff08\u53cd\u5e94\u7269\u6570\u91cf\uff09\u4e2a\u53cd\u5e94\u7269\uff0c\u5176\u4e2d\u00a0Ea\u00a0E\u662f\u6d3b\u5316\u80fd [ J\/mol]\uff0c\u00a0R\u00a0\u662f\u6c14\u4f53\u5e38\u6570 [ 8.314 J\/mol K]\u3002\u53cd\u5e94\u7269\u7684\u6d53\u5ea6 ci\u4ee5\u6469\u5c14\u6d53\u5ea6 [mol\/kg H2O] \u8868\u793a\uff0c\u53cd\u5e94\u7269\u7684\u53cd\u5e94\u9636\u6570\u7531 ai \u7ed9\u51fa\u3002F \u662f\u9891\u7387\u56e0\u5b50\u6216\u9884\u6307\u6570\u56e0\u5b50\uff0c\u5176\u5355\u4f4d\u53d6\u51b3\u4e8e\u53cd\u5e94\u7684\u5168\u53cd\u5e94\u9636\u6570\uff0c\u5373\u00a0[ 1\/(sec.molalitya-1) ]\uff0c\u5176\u4e2d a \u662f\u53cd\u5e94\u7684\u603b\u7ea7\u6570\u3002<\/p>\n

Reaction =\"\"\uff0c\u6e29\u5ea6 T \u8868\u793a\u4e3a [K]\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

GHG Option – Reaction Equilibrium and Rate PContinue Reading<\/a><\/span><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[230],"tags":[279],"_links":{"self":[{"href":"http:\/\/learncmg.cn\/index.php?rest_route=\/wp\/v2\/posts\/62550"}],"collection":[{"href":"http:\/\/learncmg.cn\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/learncmg.cn\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/learncmg.cn\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/learncmg.cn\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=62550"}],"version-history":[{"count":0,"href":"http:\/\/learncmg.cn\/index.php?rest_route=\/wp\/v2\/posts\/62550\/revisions"}],"wp:attachment":[{"href":"http:\/\/learncmg.cn\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=62550"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/learncmg.cn\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=62550"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/learncmg.cn\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=62550"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}