{"id":16933,"date":"2026-05-26T10:15:55","date_gmt":"2026-05-26T02:15:55","guid":{"rendered":"http:\/\/learncmg.cn\/?p=16933"},"modified":"2026-05-26T10:17:45","modified_gmt":"2026-05-26T02:17:45","slug":"%e5%ba%94%e7%94%a8%e6%a1%88%e4%be%8b%ef%bc%88120%ef%bc%89%ef%bc%9a%e7%94%b2%e7%83%b7%e5%90%b8%e9%99%84-%e8%a7%a3%e5%90%b8%e6%bb%9e%e5%90%8e%e5%8f%8a%e5%85%b6%e5%af%b9%e9%a1%b5%e5%b2%a9%e6%b0%94","status":"publish","type":"post","link":"http:\/\/learncmg.cn\/?p=16933","title":{"rendered":"\u5e94\u7528\u6848\u4f8b\uff08120\uff09\uff1a\u7532\u70f7\u5438\u9644-\u89e3\u5438\u6ede\u540e\u53ca\u5176\u5bf9\u9875\u5ca9\u6c14\u751f\u4ea7\u7684\u5f71\u54cd"},"content":{"rendered":"\n
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\ud83d\udcdd \u6458\u8981<\/span><\/h2>\n

\u6c14\u4f53\u89e3\u5438\u662f\u9875\u5ca9\u6c14\u85cf\u4e2d\u4e3b\u8981\u7684\u8f93\u8fd0\u673a\u5236\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u5728\u6cb9\u85cf\u6761\u4ef6\u4e0b\u8fdb\u884c\u4ea7\u6c14\u8ba1\u7b97\u65f6\uff0c\u89e3\u5438\u6c14\u7684\u5b9e\u9645\u8d21\u732e\u5e38\u5e38\u88ab\u4e0d\u52a0\u533a\u5206\u5730\u4f7f\u7528\u5438\u9644\u53c2\u6570\u6240\u63a9\u76d6\u3002\u4f20\u7edf\u4e0a\u8ba4\u4e3a\uff0c\u5728\u9875\u5ca9\u6c14\u85cf\u7684\u9ad8\u538b\u3001\u9ad8\u6e29\u6761\u4ef6\u4e0b\uff0c\u6c14\u4f53\u5438\u9644\u662f\u5b8c\u5168\u53ef\u9006\u7684\u3002\u7136\u800c\uff0c\u7814\u7a76\u8868\u660e\uff0c\u89e3\u5438\u7b49\u6e29\u7ebf\u901a\u5e38\u4e0e\u5438\u9644\u7b49\u6e29\u7ebf\u4e0d\u540c\uff0c\u4e14\u5e38\u5e38\u8868\u73b0\u51fa\u6ede\u540e\u73b0\u8c61\u3002\u4f46\u9ad8\u6e29\u9ad8\u538b\u4e0b\u8fd9\u79cd\u6ede\u540e\u884c\u4e3a\u7684\u539f\u56e0\u4ecd\u4e0d\u6e05\u695a\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5438\u9644\u6ede\u540e\u5bf9\u9875\u5ca9\u6c14\u85cf\u751f\u4ea7\u8868\u73b0\u7684\u5f71\u54cd\u6b64\u524d\u5c1a\u672a\u88ab\u7814\u7a76\u3002\u672c\u7814\u7a76\u9996\u5148\u5728\u7164\u6837\u4e0a\uff0c\u7136\u540e\u5728\u897f\u6fb3\u5927\u5229\u4e9aCanning\u76c6\u5730Ordovician Goldwyer\u7ec4\u9875\u5ca9\u6837\u54c1\u4e0a\uff0c\u6d4b\u91cf\u4e86\u7532\u70f7\u572825\u00b0C\u300140\u00b0C\u300160\u00b0C\u548c80\u00b0C\u3001\u538b\u529b\u9ad8\u8fbe7 MPa\u4e0b\u7684\u5438\u9644\u548c\u89e3\u5438\u7b49\u6e29\u7ebf\u3002\u7164\u6837\u7528\u4e8e\u6d4b\u8bd5\u72b6\u6001\u65b9\u7a0b\u5bf9\u6d4b\u91cf\u7b49\u6e29\u7ebf\u53ca\u5176\u540e\u7eed\u5e94\u7528\u7684\u5f71\u54cd\u3002\u4f7f\u7528\u7164\u6d88\u9664\u4e86\u9875\u5ca9\u7684\u590d\u6742\u6027\uff0c\u5e76\u5206\u79bb\u4e86\u4e0d\u540cEOS\u5bfc\u81f4\u7684\u6d41\u4f53\u5bc6\u5ea6\u5f71\u54cd\u3002\u4f7f\u7528\u4e86\u516d\u79cd\u6d41\u884c\u7684EOS\u8fdb\u884c\u6570\u636e\u89e3\u91ca\uff0c\u7ed3\u679c\u4e0e\u8bbe\u5907\u5185\u7f6e\u8f6f\u4ef6\uff08NIST-refprop\u00ae\uff09\u8ba1\u7b97\u7684\u7ed3\u679c\u8fdb\u884c\u4e86\u6bd4\u8f83\u3002\u9009\u62e9SBWR EOS\u7528\u4e8e\u9875\u5ca9\u6837\u54c1\u7684\u7814\u7a76\u3002\u6240\u6709\u9875\u5ca9\u6837\u54c1\u5747\u89c2\u5bdf\u5230\u65e9\u671f\u5b54\u9699\u9971\u548c\uff08\u5728\u7532\u70f7\u4e34\u754c\u538b\u529b\u9644\u8fd1\u51fa\u73b0\u6700\u5927\u8fc7\u5269\u5438\u9644\uff09\u3002\u91c7\u7528\u4e24\u6b65\u5efa\u6a21\u65b9\u6cd5\uff1a\u5148\u7528Dubinin-Radushkevich\u6a21\u578b\u62df\u5408\u8fc7\u5269\u5438\u9644\u7b49\u6e29\u7ebf\u4ee5\u83b7\u5f97\u5438\u9644\u76f8\u5bc6\u5ea6\uff0c\u518d\u7528\u5e38\u89c4Langmuir\u6a21\u578b\u63cf\u8ff0\u7edd\u5bf9\u5438\u9644\u548c\u89e3\u5438\u7b49\u6e29\u7ebf\u3002\u6240\u6709\u6837\u54c1\u5728\u6240\u6709\u6e29\u5ea6\u4e0b\u5747\u89c2\u5bdf\u5230\u663e\u8457\u7684\u6ede\u540e\u73b0\u8c61\u3002\u89e3\u5438\u7b49\u6e29\u7ebf\u4ea7\u751f\u7684\u6a21\u578b\u53c2\u6570\u4f4e\u4e8e\u76f8\u5e94\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002Langmuir\u4f53\u79ef\u4e0eTOC\u542b\u91cf\u6b63\u76f8\u5173\uff0c\u4f46\u4e0e\u603b\u7c98\u571f\u542b\u91cf\u65e0\u663e\u8457\u76f8\u5173\u3002\u7c98\u571f\u4e0eTOC\u7684\u6bd4\u503c\uff08COC\uff09\u4f5c\u4e3a\u5355\u4e00\u9884\u6d4b\u56e0\u5b50\u4e0eLangmuir\u4f53\u79ef\u663e\u793a\u51fa\u826f\u597d\u7684\u76f8\u5173\u6027\u3002\u6700\u540e\uff0c\u4f7f\u7528CMG-GEM\u00ae\u5f00\u53d1\u4e86\u7ec4\u5206\u4e09\u7ef4\u591a\u91cd\u76f8\u4e92\u4f5c\u7528\u5d4c\u5957\u8fde\u7eed\u4f53\uff08MINC\uff09\u6a21\u578b\uff0c\u4ee5\u6d4b\u8bd5\u89c2\u5bdf\u5230\u7684\u6ede\u540e\u73b0\u8c61\u5728\u6cb9\u85cf\u6761\u4ef6\u4e0b\u5bf9\u9875\u5ca9\u6c14\u751f\u4ea7\u7684\u5f71\u54cd\u3002\u6a21\u62df\u7ed3\u679c\u8868\u660e\uff0c\u5982\u679c\u4e0d\u8003\u8651\u6c14\u4f53\u5438\u9644\uff0c\u4ea7\u6c14\u91cf\u53ef\u80fd\u88ab\u663e\u8457\u4f4e\u4f30\uff0c\u800c\u4f7f\u7528\u5438\u9644\u7b49\u6e29\u7ebf\u4ee3\u66ff\u89e3\u5438\u7b49\u6e29\u7ebf\u53ef\u80fd\u5bfc\u81f4\u4ea7\u6c14\u6027\u80fd\u7684\u9ad8\u4f30\u3002<\/span><\/p>\n

\ud83d\udda5\ufe0f CMG\u8f6f\u4ef6\u5e94\u7528\u60c5\u51b5\u603b\u7ed3<\/span><\/h2>\n
\n\n\n\n\n\n\n\n\n\n\n\n\n
\u9879\u76ee<\/span><\/th>\n\u5185\u5bb9<\/span><\/th>\n<\/tr>\n<\/thead>\n
\u6240\u7528\u8f6f\u4ef6<\/span><\/strong><\/td>\nCMG-GEM\u00ae<\/span><\/strong>\uff082016\u7248\u672c\uff09\uff1a\u7ec4\u5206\u4e0e\u975e\u4f20\u7edf\u6cb9\u85cf\u6a21\u62df\u5668\uff0c\u7528\u4e8e\u9875\u5ca9\u6c14\u751f\u4ea7\u7684\u6570\u503c\u6a21\u62df\uff0c\u7814\u7a76\u5438\u9644\u6ede\u540e\u5bf9\u4ea7\u6c14\u7684\u5f71\u54cd<\/span><\/td>\n<\/tr>\n
\u6a21\u578b\u7c7b\u578b<\/span><\/strong><\/td>\n\u2022 \u4e09\u7ef4\u3001\u5355\u76f8\u3001\u591a\u91cd\u76f8\u4e92\u4f5c\u7528\u5d4c\u5957\u8fde\u7eed\u4f53\uff08MINC\uff09\u6a21\u578b\uff08Pruess and Narasimhan, 1985\uff09<\/span>
\u2022 \u57fa\u4e8eGEM\u793a\u4f8b\u6570\u636e\u96c6\u201cFractured Gas Reservoir with MINC\u201d\uff08GMFRR005.DAT\uff09<\/span>
\u2022 \u5355\u4e95\u6a21\u578b\uff0c\u5747\u5300\u5206\u5e03\u81ea\u7136\u88c2\u7f1d\uff0c\u5782\u76f4\u4e8eI\u548cJ\u65b9\u5411\u8d2f\u7a7f\u6574\u4e2a\u50a8\u5c42\u539a\u5ea6<\/span><\/td>\n<\/tr>\n
\u6a21\u62df\u5bf9\u8c61<\/span><\/strong><\/td>\n\u9875\u5ca9\u6c14\u50a8\u5c42\uff08\u57fa\u4e8eGoldwyer\u7ec4\u9875\u5ca9\u6837\u54c1\u7279\u6027\uff09\uff0c\u6a21\u62df10\u5e74\u751f\u4ea7\u5468\u671f<\/span><\/td>\n<\/tr>\n
\u5e94\u7528\u65b9\u5f0f<\/span><\/strong><\/td>\n\u2022\u00a0<\/span>\u57fa\u7840\u6a21\u578b\u5efa\u7acb<\/span><\/strong>\uff1a\u4f7f\u7528GEM\u5efa\u7acb\u201c\u65e0\u5438\u9644\u201d\u57fa\u7840\u6848\u4f8b\uff0c\u4e0d\u4f7f\u7528\u4efb\u4f55\u5438\u9644\/\u89e3\u5438\u53c2\u6570<\/span>
\u2022\u00a0<\/span>\u5438\u9644\u6848\u4f8b<\/span><\/strong>\uff1a\u4f7f\u7528\u572880\u00b0C\u4e0b\u6d4b\u5f97\u7684\u5438\u9644Langmuir\u53c2\u6570\uff08\u88684.4\uff09<\/span>
\u2022\u00a0<\/span>\u89e3\u5438\u6848\u4f8b<\/span><\/strong>\uff1a\u4f7f\u7528\u572880\u00b0C\u4e0b\u6d4b\u5f97\u7684\u89e3\u5438Langmuir\u53c2\u6570\uff08\u88684.4\uff09<\/span>
\u2022\u00a0<\/span>\u5173\u952e\u8bcd\u4f7f\u7528<\/span><\/strong>\uff1aGEM\u4f7f\u7528<\/span>ADGMAXC<\/code>\u548c<\/span>ADGCSTC<\/code>\u5173\u952e\u8bcd\u5206\u522b\u5b9a\u4e49Langmuir\u4f53\u79ef\u548cLangmuir\u538b\u529b\u7684\u5012\u6570\uff0c\u7528\u4e8e\u6a21\u62df\u751f\u4ea7\u8ba1\u7b97\u4e2d\u7684\u89e3\u5438\u8fc7\u7a0b<\/span>
\u2022\u00a0<\/span>\u5bf9\u6bd4\u5206\u6790<\/span><\/strong>\uff1a\u57fa\u7840\u6848\u4f8b\uff08\u65e0\u5438\u9644\uff09\u4e0e\u5438\u9644\u6848\u4f8b\u3001\u89e3\u5438\u6848\u4f8b\u8fdb\u884c\u5bf9\u6bd4\uff0c\u91cf\u5316\u5438\u9644\u6ede\u540e\u5bf9\u4ea7\u6c14\u7684\u5f71\u54cd<\/span><\/td>\n<\/tr>\n
\u57fa\u7840\u6a21\u578b\u53c2\u6570<\/span><\/strong>\uff08\u88685.1\uff09<\/span><\/td>\n\u2022 \u50a8\u5c42\u9762\u79ef\uff1a1378 ft \u00d7 1378 ft<\/span>
\u2022 \u50a8\u5c42\u539a\u5ea6\uff1a66 ft<\/span>
\u2022 \u5c42\u6570\uff1a1<\/span>
\u2022 \u521d\u59cb\u50a8\u5c42\u538b\u529b\uff1a2750 psi<\/span>
\u2022 \u50a8\u5c42\u6e29\u5ea6\uff1a176\u00b0F<\/span>
\u2022 \u521d\u59cb\u542b\u6c14\u9971\u548c\u5ea6\uff1a100%<\/span>
\u2022 \u57fa\u8d28\u5b54\u9699\u5ea6\uff1a0.04\uff0c\u57fa\u8d28\u6e17\u900f\u7387\uff1a1\u00d710\u207b\u2075 mD<\/span>
\u2022 \u88c2\u7f1d\u5b54\u9699\u5ea6\uff1a1\u00d710\u207b\u00b3\uff0c\u88c2\u7f1d\u6e17\u900f\u7387\uff1a1\u00d710\u207b\u00b3 mD<\/span>
\u2022 \u88c2\u7f1d\u95f4\u8ddd\uff1a26 ft<\/span>
\u2022 \u538b\u7f29\u7cfb\u6570\uff1a1\u00d710\u207b\u2076 psi\u207b\u00b9<\/span>
\u2022 \u5ca9\u77f3\u5bc6\u5ea6\uff1a2.65 g\/cc<\/span>
\u2022 \u751f\u4ea7\u4e95\u6570\uff1a1<\/span>
\u2022 \u4e95\u7b52\u534a\u5f84\uff1a0.12 ft<\/span>
\u2022 \u6700\u5c0f\u6d41\u52a8\u4e95\u5e95\u538b\u529b\uff1a350 psi<\/span>
\u2022 \u6a21\u62df\u65f6\u957f\uff1a10\u5e74<\/span><\/td>\n<\/tr>\n
\u9875\u5ca9\u6837\u54c1\u7279\u6027<\/span><\/strong>\uff08\u7b2c2\u7ae0\uff09<\/span><\/td>\n\u2022 8\u4e2a\u6837\u54c1\uff0cTOC\u542b\u91cf\uff1a0.28-4.16 wt.%<\/span>
\u2022 \u603b\u7c98\u571f\u542b\u91cf\uff1a37.1-83.5 wt.%\uff08\u4ee5\u4f0a\u5229\u77f3\/\u4e91\u6bcd\u4e3a\u4e3b\uff09<\/span>
\u2022 \u5b54\u9699\u5ea6\uff1a\u6837\u54c1\u4f9d\u8d56\u6027<\/span>
\u2022 Langmuir\u4f53\u79ef\uff0880\u00b0C\uff0c\u5438\u9644\uff09\uff1a1.88-5.25 cc\/g<\/span>
\u2022 Langmuir\u538b\u529b\uff0880\u00b0C\uff0c\u5438\u9644\uff09\uff1a4.89-8.21 MPa<\/span>
\u2022 Langmuir\u4f53\u79ef\uff0880\u00b0C\uff0c\u89e3\u5438\uff09\uff1a1.50-3.89 cc\/g<\/span>
\u2022 Langmuir\u538b\u529b\uff0880\u00b0C\uff0c\u89e3\u5438\uff09\uff1a2.38-3.61 MPa<\/span><\/td>\n<\/tr>\n
MINC\u6a21\u578b\u7279\u70b9<\/span><\/strong><\/td>\n\u2022 \u81ea\u7136\u88c2\u7f1d\u5747\u5300\u5206\u5e03<\/span>
\u2022 \u5355\u76f8\uff08\u6c14\u4f53\uff09\u6d41\u52a8<\/span>
\u2022 \u8003\u8651\u6c14\u4f53\u5438\u9644\/\u89e3\u5438<\/span>
\u2022 \u4f7f\u7528Langmuir\u6a21\u578b\u63cf\u8ff0\u5438\u9644\/\u89e3\u5438\u884c\u4e3a<\/span><\/td>\n<\/tr>\n
\u4e3b\u8981\u7ed3\u8bba<\/span><\/strong><\/td>\n\u2022 \u4e0d\u8003\u8651\u6c14\u4f53\u5438\u9644\u65f6\uff0c\u4ea7\u6c14\u91cf\u88ab\u663e\u8457\u4f4e\u4f30\uff08\u6a21\u62df\u9a8c\u8bc1\uff09<\/span>
\u2022 \u4f7f\u7528\u5438\u9644\u7b49\u6e29\u7ebf\u4ee3\u66ff\u89e3\u5438\u7b49\u6e29\u7ebf\u4f1a\u5bfc\u81f4\u4ea7\u6c14\u6027\u80fd\u7684<\/span>\u9ad8\u4f30<\/span><\/strong>
\u2022 \u5438\u9644\u6ede\u540e\u7684\u5f71\u54cd\u4e0eTOC\u542b\u91cf\u6b63\u76f8\u5173\uff08R\u00b2=0.7261\uff09<\/span>
\u2022 \u4ea7\u6c14\u9ad8\u4f30\u7a0b\u5ea6\u4e0e\u0394VL\uff08\u5438\u9644\u4e0e\u89e3\u5438Langmuir\u4f53\u79ef\u4e4b\u5dee\uff09\u5f3a\u6b63\u76f8\u5173<\/span>
\u2022 \u5438\u9644\u6ede\u540e\u7684\u5b58\u5728\u610f\u5473\u7740\u89e3\u5438Langmuir\u53c2\u6570\u66f4\u4f4e\uff0c\u5bfc\u81f4\u66f4\u4f4e\u7684\u4ea7\u6c14\u9884\u6d4b<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n

\u6587\u4e2d\u660e\u786e\u6307\u51fa\uff08Case120.pdf\uff09\uff1a<\/span><\/p>\n

\n

“A three-dimensional, single-phase, multiple interacting nested continua (MINC) model (Pruess and Narasimhan, 1985) was developed in\u00a0<\/span>CMG-GEM\u00ae<\/span><\/strong>\u00a0to study the influence of sorption hysteresis on gas production from shale rocks. The model was based on GEM’s sample dataset (GMFRR005.DAT) for ‘Fractured Gas Reservoir with MINC’ (CMG, 2016).” \uff08\u7b2c5.2\u8282\uff0c\u7b2c73\u9875\uff09<\/span><\/p>\n<\/blockquote>\n

\n

“GEM uses the keywords ‘ADGMAXC’ and ‘ADGCSTC’ to define the Langmuir volume and the reciprocal of Langmuir pressure needed for simulating the desorption process for gas production calculations (CMG, 2016).” \uff08\u7b2c5.2\u8282\uff0c\u7b2c73\u9875\uff09<\/span><\/p>\n<\/blockquote>\n

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\u53c2\u8003\u6587\u732e[174]\uff1aCMG (2016). GEM (Compositional & Unconventional Reservoir Simulator) USER GUIDE.<\/span><\/p>\n<\/blockquote>\n

\ud83e\uddea \u6a21\u62df\u65b9\u6848\u4e0e\u4e3b\u8981\u7ed3\u679c<\/span><\/h2>\n

1. \u9875\u5ca9\u6837\u54c1\u8868\u5f81\uff08\u7b2c2\u7ae0\uff09<\/span><\/h3>\n

\u6837\u54c1\u6765\u6e90<\/span><\/strong>\uff1a\u897f\u6fb3\u5927\u5229\u4e9aCanning\u76c6\u5730Ordovician Goldwyer\u7ec4\uff0cTheia 1\u4e95<\/span><\/p>\n

\u5173\u952e\u6027\u8d28<\/span><\/strong>\uff08\u88682.1\uff0c2.2\uff09\uff1a<\/span><\/p>\n

\n\n\n\n\n\n\n\n\n\n\n\n\n
\u6837\u54c1<\/span><\/th>\n\u6df1\u5ea6(m)<\/span><\/th>\nTOC (wt.%)<\/span><\/th>\n\u603b\u7c98\u571f (%)<\/span><\/th>\n\u77f3\u82f1 (%)<\/span><\/th>\n\u78b3\u9178\u76d0 (%)<\/span><\/th>\n<\/tr>\n<\/thead>\n
GTh-1<\/span><\/td>\n1201<\/span><\/td>\n0.28<\/span><\/td>\n76.58<\/span><\/td>\n15.68<\/span><\/td>\n2.11<\/span><\/td>\n<\/tr>\n
GTh-2<\/span><\/td>\n1390<\/span><\/td>\n1.26<\/span><\/td>\n83.50<\/span><\/td>\n12.42<\/span><\/td>\n0.25<\/span><\/td>\n<\/tr>\n
GTh-3<\/span><\/td>\n1473<\/span><\/td>\n3.20<\/span><\/td>\n74.28<\/span><\/td>\n17.39<\/span><\/td>\n0.42<\/span><\/td>\n<\/tr>\n
GTh-4<\/span><\/td>\n1478<\/span><\/td>\n2.82<\/span><\/td>\n67.52<\/span><\/td>\n20.11<\/span><\/td>\n3.93<\/span><\/td>\n<\/tr>\n
GTh-5<\/span><\/td>\n1521<\/span><\/td>\n2.76<\/span><\/td>\n37.10<\/span><\/td>\n27.11<\/span><\/td>\n29.11<\/span><\/td>\n<\/tr>\n
GTh-6<\/span><\/td>\n1531<\/span><\/td>\n0.75<\/span><\/td>\n68.44<\/span><\/td>\n12.93<\/span><\/td>\n12.71<\/span><\/td>\n<\/tr>\n
GTh-7<\/span><\/td>\n1543<\/span><\/td>\n3.86<\/span><\/td>\n72.47<\/span><\/td>\n9.14<\/span><\/td>\n12.11<\/span><\/td>\n<\/tr>\n
GTh-8<\/span><\/td>\n1550<\/span><\/td>\n4.16<\/span><\/td>\n46.33<\/span><\/td>\n21.61<\/span><\/td>\n14.21<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n

\u4f4e\u6e29\u6c2e\u6c14\u5438\u9644\u7ed3\u679c<\/span><\/strong>\uff08\u56fe2.5-2.6\uff09\uff1a<\/span><\/p>\n

    \n
  • \n

    \u6240\u6709\u6837\u54c1\u5747\u8868\u73b0\u51faH3\u578b\u6ede\u540e\u73af\uff08IUPAC\u5206\u7c7b\uff09\uff0c\u8868\u660e\u72ed\u7f1d\u72b6\u7eb3\u7c73\u5b54\u9699<\/span><\/p>\n<\/li>\n

  • \n

    \u5b54\u9699\u5448\u53cc\u5cf0\u5206\u5e03\uff0c\u4e3b\u5cf0<\/span>~4 nm\u548c<\/span>~25 nm<\/span><\/p>\n<\/li>\n

  • \n

    \u4ecb\u5b54\uff082-50 nm\uff09\u5360\u4e3b\u5bfc<\/span><\/p>\n<\/li>\n<\/ul>\n

    COC\u53c2\u6570<\/span><\/strong>\uff08\u7c98\u571f\u4e0eTOC\u6bd4\u503c\uff0c\u5f0f2.2\uff09\uff1a<\/span><\/p>\n

      \n
    • \n

      COC = \u603b\u7c98\u571f\u542b\u91cf \/ TOC\u542b\u91cf<\/span><\/p>\n<\/li>\n

    • \n

      \u4e0eTOC\u542b\u91cf\u5f3a\u76f8\u5173\uff08\u56fe2.11\uff09\uff0c\u4f5c\u4e3aTOC\u548c\u7c98\u571f\u542b\u91cf\u7684\u7efc\u5408\u9884\u6d4b\u56e0\u5b50<\/span><\/p>\n<\/li>\n<\/ul>\n

      2. \u72b6\u6001\u65b9\u7a0b\uff08EOS\uff09\u5bf9\u5438\u9644\u7b49\u6e29\u7ebf\u7684\u5f71\u54cd\uff08\u7b2c3\u7ae0\uff09<\/span><\/h3>\n

      \u6d4b\u8bd5\u7684EOS<\/span><\/strong>\uff086\u79cd\uff09\uff1a<\/span><\/p>\n

        \n
      • \n

        PR\uff08Peng-Robinson\uff09<\/span><\/p>\n<\/li>\n

      • \n

        PR-Peneloux\uff08\u4f53\u79ef\u5e73\u79fb\uff09<\/span><\/p>\n<\/li>\n

      • \n

        SRK\uff08Soave-Redlich-Kwong\uff09<\/span><\/p>\n<\/li>\n

      • \n

        SRK-Peneloux<\/span><\/p>\n<\/li>\n

      • \n

        SBWR\uff08Soave\u4fee\u6539\u7684Benedict-Webb-Rubin\uff09<\/span><\/p>\n<\/li>\n

      • \n

        LK\uff08Lee-Kesler\uff09<\/span><\/p>\n<\/li>\n

      • \n

        \u53c2\u8003\uff1aNIST-refprop\uff08McCarty & Arp for He\uff0cSetzmann & Wagner for CH\u2084\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

        \u5173\u952e\u53d1\u73b0<\/span><\/strong>\uff08\u56fe3.3-3.7\uff0c\u88683.3\uff09\uff1a<\/span><\/p>\n

          \n
        • \n

          \u6240\u6709EOS\u8ba1\u7b97\u7684\u6c26\u6c14Z\u56e0\u5b50\u4e0eNIST-refprop\u504f\u5dee<0.25%\uff08LK\u9664\u5916\uff09<\/span><\/p>\n<\/li>\n

        • \n

          \u81ea\u7531\u7a7a\u95f4\u4f53\u79ef\u504f\u5dee\u76f4\u63a5\u5f71\u54cd\u5438\u9644\u91cf\uff08\u00b10.25%\u81ea\u7531\u7a7a\u95f4\u53d8\u5316\u2192\u221310%\u5438\u9644\u91cf\u53d8\u5316\uff09<\/span><\/p>\n<\/li>\n

        • \n

          \u7532\u70f7Z\u56e0\u5b50\u504f\u5dee\u968f\u538b\u529b\u589e\u5927\u800c\u589e\u5927<\/span><\/p>\n<\/li>\n

        • \n

          SBWR-EOS<\/span><\/strong>\u4e0eNIST-refprop\u7684\u504f\u5dee\u6700\u5c0f\uff0c\u88ab\u9009\u7528\u4e8e\u9875\u5ca9\u6837\u54c1\u7814\u7a76<\/span><\/p>\n<\/li>\n

        • \n

          \u6ede\u540e\u7c7b\u578b\u4e0eEOS\u76f8\u5173\uff1a\u8d1f\u504f\u5deeEOS\uff08PR\u3001PR-Peneloux\u3001SBWR\uff09\u2192\u6b63\u6ede\u540e\uff1b\u6b63\u504f\u5deeEOS\uff08SRK\u3001SRK-Peneloux\u3001LK\uff09\u2192\u8d1f\u6ede\u540e<\/span><\/p>\n<\/li>\n<\/ul>\n

          3. \u9875\u5ca9\u9ad8\u538b\u7532\u70f7\u5438\u9644\/\u89e3\u5438\u7b49\u6e29\u7ebf\uff08\u7b2c4.3\u8282\uff09<\/span><\/h3>\n

          \u8fc7\u5269\u5438\u9644\u7279\u5f81<\/span><\/strong>\uff08\u56fe4.2\uff09\uff1a<\/span><\/p>\n

            \n
          • \n

            \u6240\u6709\u6837\u54c1\u5728~5 MPa\uff08\u63a5\u8fd1\u7532\u70f7\u4e34\u754c\u538b\u529b4.6 MPa\uff09\u5904\u51fa\u73b0\u6700\u5927\u8fc7\u5269\u5438\u9644<\/span><\/p>\n<\/li>\n

          • \n

            \u65e9\u671f\u5b54\u9699\u9971\u548c\u5f52\u56e0\u4e8e\u9ad8\u4f0a\u5229\u77f3\u542b\u91cf\u5835\u585e\u6709\u673a\u5b54\u9699<\/span><\/p>\n<\/li>\n

          • \n

            \u6e29\u5ea6\u5347\u9ad8\uff0c\u5438\u9644\u91cf\u964d\u4f4e<\/span><\/p>\n<\/li>\n<\/ul>\n

            DR\u6a21\u578b\u62df\u5408\u7ed3\u679c<\/span><\/strong>\uff08\u88684.2\uff09\uff1a<\/span><\/p>\n

              \n
            • \n

              \u6700\u5927\u7edd\u5bf9\u5438\u9644\u91cfV\u2080\uff1a1.11-4.08 cc\/g\uff0880\u00b0C\uff09<\/span><\/p>\n<\/li>\n

            • \n

              \u5438\u9644\u76f8\u5bc6\u5ea6\u03c1_ads\uff1a75.95-240.54 kg\/m\u00b3<\/span><\/p>\n<\/li>\n

            • \n

              \u5438\u9644\u7279\u5f81\u80fd\u91cfE\uff1a5.7-7.2 kJ\/mol\uff08\u7269\u7406\u5438\u9644\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

              Langmuir\u6a21\u578b\u62df\u5408\u7ed3\u679c<\/span><\/strong>\uff08\u88684.4\uff0c80\u00b0C\uff09\uff1a<\/span><\/p>\n

              \n\n\n\n\n\n\n\n\n\n\n\n\n
              \u6837\u54c1<\/span><\/th>\nV_L\u5438\u9644(cc\/g)<\/span><\/th>\nP_L\u5438\u9644(MPa)<\/span><\/th>\nV_L\u89e3\u5438(cc\/g)<\/span><\/th>\nP_L\u89e3\u5438(MPa)<\/span><\/th>\n<\/tr>\n<\/thead>\n
              GTh-1<\/span><\/td>\n1.88<\/span><\/td>\n5.63<\/span><\/td>\n1.50<\/span><\/td>\n2.38<\/span><\/td>\n<\/tr>\n
              GTh-2<\/span><\/td>\n2.63<\/span><\/td>\n4.89<\/span><\/td>\n2.37<\/span><\/td>\n2.87<\/span><\/td>\n<\/tr>\n
              GTh-3<\/span><\/td>\n3.09<\/span><\/td>\n5.55<\/span><\/td>\n2.19<\/span><\/td>\n1.76<\/span><\/td>\n<\/tr>\n
              GTh-4<\/span><\/td>\n4.01<\/span><\/td>\n7.10<\/span><\/td>\n2.76<\/span><\/td>\n2.45<\/span><\/td>\n<\/tr>\n
              GTh-5<\/span><\/td>\n3.24<\/span><\/td>\n5.69<\/span><\/td>\n2.45<\/span><\/td>\n2.61<\/span><\/td>\n<\/tr>\n
              GTh-6<\/span><\/td>\n2.78<\/span><\/td>\n5.79<\/span><\/td>\n2.23<\/span><\/td>\n2.51<\/span><\/td>\n<\/tr>\n
              GTh-7<\/span><\/td>\n4.60<\/span><\/td>\n8.21<\/span><\/td>\n3.18<\/span><\/td>\n3.56<\/span><\/td>\n<\/tr>\n
              GTh-8<\/span><\/td>\n5.25<\/span><\/td>\n7.46<\/span><\/td>\n3.89<\/span><\/td>\n3.61<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n

              \u5173\u952e\u89c2\u5bdf<\/span><\/strong>\uff1a<\/span><\/p>\n

                \n
              • \n

                \u6240\u6709\u6837\u54c1\u5747\u8868\u73b0\u51fa\u663e\u8457\u6ede\u540e\uff08\u89e3\u5438\u7b49\u6e29\u7ebf\u4f4e\u4e8e\u5438\u9644\u7b49\u6e29\u7ebf\uff09<\/span><\/p>\n<\/li>\n

              • \n

                \u89e3\u5438Langmuir\u4f53\u79ef\u6bd4\u5438\u9644\u4f4e~20-40%<\/span><\/p>\n<\/li>\n

              • \n

                \u89e3\u5438Langmuir\u538b\u529b\u6bd4\u5438\u9644\u4f4e~40-70%<\/span><\/p>\n<\/li>\n<\/ul>\n

                4. Langmuir\u53c2\u6570\u4e0e\u5ca9\u77f3\u6027\u8d28\u7684\u5173\u7cfb\uff08\u7b2c4.3.5-4.3.6\u8282\uff09<\/span><\/h3>\n

                V_L\u4e0eTOC\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe4.7\uff0c\u5f0f4.12\uff09\uff1a<\/span><\/p>\n

                  \n
                • \n

                  V_L,ads(TOC,T) = 3.0199 + 0.9240\u00d7TOC – 0.0027\u00d7T\u00d7(TOC + 3.00)<\/span><\/p>\n<\/li>\n

                • \n

                  V_L,des(TOC,T) = 2.2093 + 0.6861\u00d7TOC – 0.0030\u00d7T\u00d7(TOC + 2.79)<\/span><\/p>\n<\/li>\n<\/ul>\n

                  V_L\u4e0eCOC\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe4.9\uff0c\u5f0f4.13\uff09\uff1a<\/span><\/p>\n

                    \n
                  • \n

                    V_L,ads(COC,T) = 6.5456 + 0.0144\u00d7COC – 6.7\u00d710\u207b\u2075\u00d7T\u00d7(COC – 438.4)<\/span><\/p>\n<\/li>\n

                  • \n

                    V_L,des(COC,T) = 4.5215 + 0.0104\u00d7COC – 5.2\u00d710\u207b\u2075\u00d7T\u00d7(COC – 358.5)<\/span><\/p>\n<\/li>\n<\/ul>\n

                    V_L\u4e0e\u7c98\u571f\u542b\u91cf\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe4.8\uff09\uff1a<\/span><\/p>\n

                      \n
                    • \n

                      \u5f31\u8d1f\u76f8\u5173\u6216\u65e0\u663e\u8457\u76f8\u5173\uff08R\u00b2\u8f83\u4f4e\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

                      P_L\u4e0eV_L\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe4.10\uff0c\u5f0f4.14-4.16\uff09\uff1a<\/span><\/p>\n

                        \n
                      • \n

                        P_L = m\u2081\u00d7V_L + c\u2081<\/span><\/p>\n<\/li>\n

                      • \n

                        m\u2081\u548cc\u2081\u4e3a\u6e29\u5ea6\u7684\u4e8c\u6b21\u51fd\u6570\uff08\u88684.5\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

                        5. \u6570\u503c\u6a21\u62df\uff1a\u5438\u9644\u6ede\u540e\u5bf9\u4ea7\u6c14\u7684\u5f71\u54cd\uff08\u7b2c5\u7ae0\uff09<\/span><\/h3>\n

                        \u6a21\u62df\u60c5\u666f<\/span><\/strong>\uff08\u88685.2\uff09\uff1a<\/span><\/p>\n

                          \n
                        • \n

                          \u57fa\u7840\u6848\u4f8b\uff08\u65e0\u5438\u9644\uff09\uff1aOGIP=862 MMSCF<\/span><\/p>\n<\/li>\n

                        • \n

                          \u5438\u9644\u6848\u4f8b\uff1a\u4f7f\u7528\u5438\u9644Langmuir\u53c2\u6570\uff0880\u00b0C\uff09<\/span><\/p>\n<\/li>\n

                        • \n

                          \u89e3\u5438\u6848\u4f8b\uff1a\u4f7f\u7528\u89e3\u5438Langmuir\u53c2\u6570\uff0880\u00b0C\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

                          OGIP\u4e2d\u5438\u9644\u6c14\u5360\u6bd4<\/span><\/strong>\uff08\u88685.2\uff09\uff1a<\/span><\/p>\n

                            \n
                          • \n

                            GTh-1\uff08\u4f4eTOC\uff09\uff1a36.0%<\/span><\/p>\n<\/li>\n

                          • \n

                            GTh-8\uff08\u9ad8TOC\uff09\uff1a59.4%<\/span><\/p>\n<\/li>\n

                          • \n

                            TOC\u8d8a\u9ad8\uff0c\u5438\u9644\u6c14\u5360\u6bd4\u8d8a\u5927<\/span><\/p>\n<\/li>\n<\/ul>\n

                            10\u5e74\u7d2f\u8ba1\u4ea7\u6c14\u7ed3\u679c<\/span><\/strong>\uff08\u56fe5.1\uff09\uff1a<\/span><\/p>\n

                              \n
                            • \n

                              \u57fa\u7840\u6848\u4f8b\uff08\u65e0\u5438\u9644\uff09\uff1a\u6700\u4f4e<\/span><\/p>\n<\/li>\n

                            • \n

                              \u89e3\u5438\u6848\u4f8b\uff1a\u4e2d\u7b49<\/span><\/p>\n<\/li>\n

                            • \n

                              \u5438\u9644\u6848\u4f8b\uff1a\u6700\u9ad8<\/span><\/p>\n<\/li>\n<\/ul>\n

                              \u4ea7\u6c14\u9ad8\u4f30\u7a0b\u5ea6\u4e0eTOC\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe5.3a\uff09\uff1a<\/span><\/p>\n

                                \n
                              • \n

                                \u4ea7\u6c14\u9ad8\u4f30\uff08\u5438\u9644 vs \u89e3\u5438\uff09\u4e0eTOC\u6b63\u76f8\u5173\uff0cR\u00b2=0.7261<\/span><\/p>\n<\/li>\n<\/ul>\n

                                \u4ea7\u6c14\u9ad8\u4f30\u7a0b\u5ea6\u4e0eCOC\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe5.3c\uff09\uff1a<\/span><\/p>\n

                                  \n
                                • \n

                                  \u8d1f\u76f8\u5173\uff0cR\u00b2=0.5907<\/span><\/p>\n<\/li>\n<\/ul>\n

                                  \u4ea7\u6c14\u9ad8\u4f30\u4e0e\u0394V_L\u7684\u5173\u7cfb<\/span><\/strong>\uff08\u56fe5.6b\uff09\uff1a<\/span><\/p>\n

                                    \n
                                  • \n

                                    \u5f3a\u6b63\u76f8\u5173\uff08\u5438\u9644\u6ede\u540e\u8d8a\u5927\uff0c\u4ea7\u6c14\u9ad8\u4f30\u8d8a\u4e25\u91cd\uff09<\/span><\/p>\n<\/li>\n<\/ul>\n

                                    \u2705 \u4e3b\u8981\u7ed3\u8bba<\/span><\/h2>\n
                                      \n
                                    1. \n

                                      EOS\u5bf9\u5438\u9644\u6d4b\u91cf\u7684\u663e\u8457\u5f71\u54cd<\/span><\/strong>\uff1a\u4e0d\u540cEOS\u8ba1\u7b97\u7684\u6c26\u6c14\u548c\u7532\u70f7Z\u56e0\u5b50\u5dee\u5f02\u5bfc\u81f4\u81ea\u7531\u7a7a\u95f4\u4f53\u79ef\u548c\u5438\u9644\u7b49\u6e29\u7ebf\u7684\u663e\u8457\u5dee\u5f02\uff0c\u8fdb\u800c\u5f71\u54cdLangmuir\u53c2\u6570\u548c\u50a8\u91cf\u4f30\u7b97\u3002SBWR-EOS\u4e0eNIST-refprop\u504f\u5dee\u6700\u5c0f\uff0c\u88ab\u63a8\u8350\u7528\u4e8e\u6b64\u7c7b\u7814\u7a76\u3002<\/span><\/p>\n<\/li>\n

                                    2. \n

                                      \u9875\u5ca9\u7684\u65e9\u671f\u5b54\u9699\u9971\u548c<\/span><\/strong>\uff1aGoldwyer\u9875\u5ca9\u56e0\u9ad8\u4f0a\u5229\u77f3\u542b\u91cf\uff0c\u5728~5 MPa\uff08\u63a5\u8fd1\u7532\u70f7\u4e34\u754c\u538b\u529b\uff09\u5373\u8fbe\u5230\u6700\u5927\u8fc7\u5269\u5438\u9644\uff0c\u8fdc\u4f4e\u4e8e\u5e38\u89c1\u6587\u732e\u503c\uff0810-15 MPa\uff09\uff0c\u9700\u91c7\u7528DR+Langmuir\u4e24\u6b65\u6cd5\u5efa\u6a21\u3002<\/span><\/p>\n<\/li>\n

                                    3. \n

                                      \u663e\u8457\u7684\u5438\u9644\u6ede\u540e<\/span><\/strong>\uff1a\u6240\u6709\u6837\u54c1\u5728\u6240\u6709\u6e29\u5ea6\u4e0b\u5747\u8868\u73b0\u51fa\u663e\u8457\u6ede\u540e\uff08\u89e3\u5438\u7b49\u6e29\u7ebf\u4f4e\u4e8e\u5438\u9644\u7b49\u6e29\u7ebf\uff09\uff0c\u89e3\u5438Langmuir\u4f53\u79ef\u548c\u538b\u529b\u5747\u4f4e\u4e8e\u5438\u9644\u503c\uff08\u5206\u522b\u4f4e20-40%\u548c40-70%\uff09\u3002<\/span><\/p>\n<\/li>\n

                                    4. \n

                                      Langmuir\u53c2\u6570\u7684\u9884\u6d4b\u6a21\u578b<\/span><\/strong>\uff1a\u9996\u6b21\u5efa\u7acb\u4e86\u5438\u9644\u548c\u89e3\u5438\u8fc7\u7a0b\u7684Langmuir\u4f53\u79ef\u4e0eTOC\u3001COC\u7684\u6e29\u5ea6\u76f8\u5173\u9884\u6d4b\u6a21\u578b\uff08\u5f0f4.12-4.13\uff09\uff0c\u4ee5\u53caLangmuir\u538b\u529b\u4e0eLangmuir\u4f53\u79ef\u7684\u6e29\u5ea6\u76f8\u5173\u5173\u7cfb\uff08\u5f0f4.14-4.16\uff09\u3002<\/span><\/p>\n<\/li>\n

                                    5. \n

                                      \u5438\u9644\u6ede\u540e\u5bf9\u4ea7\u6c14\u7684\u5b9a\u91cf\u5f71\u54cd<\/span><\/strong>\uff1a<\/span><\/p>\n